I would make sure your baffle seal is in good shape and not leaking air past the fins.
As most above state, setting the fuel flows correctly is a must for our 231 engines.
If your CHTs are getting to 460dF you will be doing(paying) top overhauls every 300-600 hours, so rethink that part of the POH. Crazy part on PoH is there are written when our aircraft was new, but they have zero updates on a better way to run your engine. This is where MS can help save you and your engine.
We have learned an incredible amount over the years on proper fuel flow set up and heat control to extend cylinder life. High heat & high pressure kills our cylinders.
Thank you, Mike Bush, and Paul Kortopates (he is here on MS) for helping get the word out.
My GB(no intercooler/no waste gate) fuel flows are set to 25.7gpm at 2700RPM, 40inMP. I takeoff and climb at 100% power to altitude (normally 16K-17K). That gets me a TIT of ~1425dF, and CHTs 300dF - 330dF This max fuel flow is 1gpm higher than the TC SID97-3G calls out (24.7gpm) but is an accepted change first pushed by RAM aircraft and everyone that knows our engines.
If my CHTs in the climb are approaching 380dF on a hot day I increase air speed. If its 110dF OAT I am climbing at ~500ft min. My engine is at 1950hrs and two jugs were changed before I bought it(@1200hr) and I have changed one jug for a crack in the exhaust (due to a casting void).
Jim