Thank you all for your suggestions and comments that's really helpful. I do have backup O2, set the MEA into my G500 and monitor my pulse ox and CO continuously. Learned a long time ago in the Army to follow the P.A.C.E acronym when dealing with high risk situations that require a plan if all goes to hell. (Primary, Alternate, Contingent, Emergent). I go over the Rockies a lot so I need to be at 20 and 21 for my personal safety margin but I come down to the teens as soon as I'm over the highest parts of the trip.
I do preflight my TKS usually once a month or so and don't mind letting the fluid come out all over the ramp to make sure every inch is weeping fluid.
I just found it really curious the only trace ice on the airframe was where the TKS fluid was. The Spot on the wing behind the landing lights (no TKS strip there) was clean as a whistle. I know that TKS fluid has some water in it according to the manufacture. This made me believe that at -35F the small amount of water was clumping on the wing. It slid off and was not building up. I think Next time im that cold and in clear air I'm gonna see if it happens again.
Some one asked about oil temp at 25000 oat -35F 75% power and 125 rich of peak oil temp was 185 hottest cht was 360, TIT 1550. IT was just really interesting to see the response of the systems to really cold really high flight . Needless to say It is not my plan to routinely travel that high or that cold.