Thank you for the responses to my question. It was as I suspected that the capacitive sensors in the tank only indicate up to 44.5 usg per side even though the tank holds 51 usg useable. What I don't understand is why the indicators don't stay on the Full indication until the actual quantity reaches 44.5 usg. From what I see, it is not a linear progression.
The flow indication & totaliser are very accurate and as mentioned previously, use that from a known quantity (physical marks on the filler tabs) to ensure I know exactly how much fuel is in the tanks. When refuelling, the amounts are always within 0.2 usg of the anticipated fuel upload.
I have since had another look at the 'setup' within the G1000 and have confirmed that mine is selected to the 102 useable as per the STC so there is nothing more I can do although I feel sure that as mentioned in other posts above, that this issue could be addressed by the V14 software upgrade.